含氮、硫雜環(huán)配體及其配合物的合成及結構研究.pdf

1、南京理工大學博士學位論文含氮、硫雜環(huán)配體及其配合物的合成及結構研究姓名：張江潤申請學位級別：博士專業(yè)：材料學指導教師：汪信陸路德20020314甍文摘耍博士論文AbstractAseriesofnewdinuclearmacrocycliccomplexes[M2L1(C104)2]havebeensynthesizedby【22]Schiffbasecondensationbetweensodium26一diformyt一4一chlo

2、rphenolate(sdcp)andthereduced1：1Schiffbaseoftris(2aminoethyl)amine(tren)and2acetylpyridineinthepresenceofM(C104)26H20(M=Mn”，Cd”，Zn”，Cu“)ThecomplexeshavebeencharacterizedbyspectralanalysisThestructureofMn2L‘(C104)2wasdete

3、rminedbyX—rayCrystallographyNN—bis(2arninoethyl)N一(2nitrobenzyl)aminewiththreehydrochloricacidwassynthesizedfromni仃obenzeneandbiethyltriamine，andwasusedtosynthesizethemacrocycliccomplexesthroughtheSchiffbasecomdensationw

4、ith26一diformyl一4methylphenolate(L2)and26diformyl一4一chlorphenolate(sdcp)(L3)AllthecomplexeswithmacrocyclicligandsL2andL3werecharacterizedbyspectralanalysisTri(2formylphenoxymethyl)aminewassynthesizedandwasusedintheSchiffb

5、asecondensation、vitl13一propylenediamineandtrentoprepareformacrocyclicligandL4andchelateligandL5andtheircomplexes，BoththeligandsandthecomplexeswerecharacterizedbyspectralanalysisComplexeswithmorpholinedithiocarbamatos，S’l

6、igandandpyrrolyldithioearbamato—S，S’ligandweresynthesizedandwerecharacterizedbyspectralanalysisThestructureoftris(4_morpholinedithiocarbamato—S，S’)Cobalt(III)acetonitrilesolvatecomplex：【Co(S2CNC4H80)3]CH]CNweredetermined

7、byX—raycrystallography12一bi(2’一formylphenoxy)ethane(C16H1404)hasbeensynthesizedbynucleophilicsubstitutionreactionofsalicylaldehydeand12一ethylenedioxideoaminophenol(C】2H14N202)hasbeensynthesizedbyhydrogenationreactionofni

8、trophen01ThecrystalandmolecularstructuresofboththecompoundsweredeterminedbyX—raycrystallographyAseriesofcomplexeswithSalenligandweresynthesizedbytheSchiffbasecondensationreactionofOobenzenediamine，salicylaldehydeandpyraz